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Degradation of refractory organics in concentrated leachate by the Fenton process: Central compositedesign for process optimization

Senem Yazici Guvenc, Gamze Varank

《环境科学与工程前沿（英文）》 2021年 第15卷 第1期 doi: 10.1007/s11783-020-1294-1

摘要： Abstract • 90% total COD, 95.3% inert COD and 97.2% UV254 were removed. • High R2 values (over 95%) for all responses were obtained with CCD. • Operational cost was calculated to be 0.238 €/g CODremoved for total COD removal. • Fenton oxidation was highly-efficient method for inert COD removal. • BOD5/COD ratio of leachate concentrate raised from 0.04 to 0.4. The primary aim of this study is inert COD removal from leachate nanofiltration concentrate because of its high concentration of resistant organic pollutants. Within this framework, this study focuses on the treatability of leachate nanofiltration concentrate through Fenton oxidation and optimization of process parameters to reach the maximum pollutant removal by using response surface methodology (RSM). Initial pH, Fe2+ concentration, H2O2/Fe2+ molar ratio and oxidation time are selected as the independent variables, whereas total COD, color, inert COD and UV254 removal are selected as the responses. According to the ANOVA results, the R2 values of all responses are found to be over 95%. Under the optimum conditions determined by the model (pH: 3.99, Fe2+: 150 mmol/L, H2O2/Fe2+: 3.27 and oxidation time: 84.8 min), the maximum COD removal efficiency is determined as 91.4% by the model. The color, inert COD and UV254 removal efficiencies are determined to be 99.9%, 97.2% and 99.5%, respectively, by the model, whereas the total COD, color, inert COD and UV254 removal efficiencies are found respectively to be 90%, 96.5%, 95.3% and 97.2%, experimentally under the optimum operating conditions. The Fenton process improves the biodegradability of the leachate NF concentrate, increasing the BOD5/COD ratio from the value of 0.04 to the value of 0.4. The operational cost of the process is calculated to be 0.238 €/g CODremoved. The results indicate that the Fenton oxidation process is an efficient and economical technology in improvement of the biological degradability of leachate nanofiltration concentrate and in removal of resistant organic pollutants.

关键词： Concentrated leachate     Fenton oxidation     Central composite design     Biodegradability     Inert COD    

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Development of a multi-component drug from turmeric using central composite design

Xiaohang ZHANG,Shengnan HAN,Yan LI,Jianlan JIANG

《化学科学与工程前沿（英文）》 2014年 第8卷 第3期   页码 362-368 doi: 10.1007/s11705-014-1439-5

摘要： A methodology to develop multi-component drugs based on traditional Chinese medicines has been developed using central composite design. Several active components from the traditional Chinese medicine turmeric were chosen for use in a multi-component antitumor drug. Response surface methodology based on a central composite design was applied to determine the quantitative composition-activity relationships in order to optimize the amount of each component in the drug. An MTT (3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyltetrazolium bromide) assay was used to measure the pharmacological activity as the response value. The experimental antitumor activity of the optimum combination was 92.85% in the MTT assay and superior to the activities of each single component. These results demonstrate that response surface methodology based on a central composite design is suitable for the design of multi-component drugs.

关键词： multi-component drug development     central composite design     turmeric     curcuminoids    

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Statistical modeling of radiolytic (

G. S. Muthu Iswarya, B. Nirkayani, A. Kavithakani, V. C. Padmanaban

《环境科学与工程前沿（英文）》 2019年 第13卷 第3期 doi: 10.1007/s11783-019-1126-3

摘要：

Linear, interactive and quadratic effects of process parameters were studied.

Degradation of Ofloxacin (Ofx) was related with G value of irradiation process.

The synergistic effect of H2O2 on lower dose of g-irradiation was established.

The process follows pseudo first order with dose constant (d = 0.232 kGy–1).

关键词： Ofloxacin     Gamma irradiation     Face centered central composite design     Reaction kinetics     Gas Chromatography-Mass spectrum    

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Removal of malachite green from aqueous solution by sorption on hydrilla verticillata biomass using response surface methodology

R. RAJESHKANNAN, N. RAJAMOHAN, M. RAJASIMMAN

《化学科学与工程前沿（英文）》 2009年 第3卷 第2期   页码 146-154 doi: 10.1007/s11705-009-0007-x

摘要： In the present study, the effect of adsorbent dose, pH, temperature, initial dye concentration and contact time on malachite green removal from an aqueous medium using hydrilla verticillata biomass has been investigated. The central composite face-centered experimental design (CFCD) in response surface methodology (RSM) was used for designing the experiments as well as for full response surface estimation. The optimum conditions for maximum removal of malachite green from an aqueous solution of 75.52 mg/L were as follows: adsorbent dose (11.14 g/L), pH (8.4), temperature (48.4°C) and contact time (194.5 min). This was evidenced by the higher value of coefficient of determination ( =0.9158).

关键词： response surface methodology     hydrilla verticillata     malachite green     adsorption     central composite design    

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Trial design of arch bridge of composite box section with steel web-concrete flange

Jiangang WEI, Qingwei HUANG, Baochun CHEN,

《结构与土木工程前沿（英文）》 2010年 第4卷 第3期   页码 370-375 doi: 10.1007/s11709-010-0073-7

摘要： The concrete arch bridge is a natural and appropriate structural solution, aesthetically pleasing and easily integrated into the environment, especially in mountainous and island areas. However, construction difficulty and cost will increase with heavy self-weight when the span enlarges. A potential solution is to use a composite box arch ring with steel web-concrete flange. Taking Wanzhou Yangtze River Bridge (the longest concrete arch bridge in the world with a main span of 420 m) as a prototype, trial designs of a composite box arch with steel webs (including corrugated steel webs and plain steel webs) and concrete flanges were carried out. Comparison of quantities and structural behaviors of the prototype concrete arch with the two trial designed composite arch was presented. It is shown that the self-weight of the composite arch can reduce about 28% and the structures can meet the design requirements, therefore it is possible to use the two composite arches in long span arch bridges.

关键词： steel webs     concrete     box arch     trial design     structural behaviors     finite element method    

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Design of composite flywheel rotor

BAI Yue, GAO Qingjia, LI Haiwen, WU Yihui, XUAN Ming

《机械工程前沿（英文）》 2008年 第3卷 第3期   页码 288-292 doi: 10.1007/s11465-008-0045-y

摘要： A design method for a flywheel rotor composed of a composite rim and a metal hub is proposed by studying the connection between the rotor and the driving machine. The influence of some factors such as the rotor material, configuration, connection, and fracture techniques on energy density is analyzed. The results show that the ratio of the inner radius to outer radius of the rim is the key factor, and is determined by the rim material. Optimizing the hub can further efficiently improve energy density. The composite flywheel rotor is produced and its rotation stress has been tested at the speed of 20 krpm. The emulation results are consistent with testing results, which proves that the introduced design method is useful.

关键词： introduced     useful     density     composite     driving machine    

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Analysis and design of steel-concrete composite sandwich systems subjected to extreme loads

Kazi Md Abu SOHEL, Jat Yuen Richard LIEW, Min Hong ZHANG

《结构与土木工程前沿（英文）》 2011年 第5卷 第3期   页码 278-293 doi: 10.1007/s11709-011-0120-z

摘要： This paper presents the design guide based on analytical, numerical and experimental investigation of Steel-concrete-steel (SCS) sandwich structural members comprising a lightweight concrete core with density ranged from 1300 to 1445 kg/m subjected to static, impact and blast loads. The performance of lightweight sandwich members is also compared with similar members with normal weight concrete core and ultra high strength concrete core ( = 180 MPa). Novel J-hook shear connectors were invented to prevent the separation of face plates from the concrete core under extreme loads and their uses are not restricted by the concrete core thickness. Flexural and punching are the primary modes of failure under static point load. Impact test results show that the SCS sandwich panels with the J-hook connectors are capable of resisting impact load with less damage in comparison than equivalent stiffened steel plate panels. Blast tests with 100 kg TNT were performed on SCS sandwich specimens to investigate the key parameters that affect the blast resistance of SCS sandwich structure. Plastic yield line method is proposed to predict the plastic capacity and post peak large deflection of the sandwich plates. Finally, an energy balanced model is developed to analyze the global behavior of SCS sandwich panels subjected to dynamic load.

关键词： blast load     composite structure     impact load     lightweight concrete     sandwich plate     J-hook connector    

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Design concepts of an aircraft wing: composite and morphing airfoil with auxetic structures

P R BUDARAPU,Sudhir Sastry Y B,R NATARAJAN

《结构与土木工程前沿（英文）》 2016年 第10卷 第4期   页码 394-408 doi: 10.1007/s11709-016-0352-z

摘要： This paper is categorized into two parts. (1) A frame work to design the aircraft wing structure and (2) analysis of a morphing airfoil with auxetic structure. The developed design frame work in the first part is used to arrive at the sizes of the various components of an aircraft wing structure. The strength based design is adopted, where the design loads are extracted from the aerodynamic loads. The aerodynamic loads acting on a wing structure are converted to equivalent distributed loads, which are further converted point loads to arrive at the shear forces, bending and twisting moments along the wing span. Based on the estimated shear forces, bending and twisting moments, the strength based design is employed to estimate the sizes of various sections of a composite wing structure. A three dimensional numerical model of the composite wing structure has been developed and analyzed for the extreme load conditions. Glass fiber reinforced plastic material is used in the numerical analysis. The estimated natural frequencies are observed to be in the acceptable limits. Furthermore, the discussed design principles in the first part are extended to the design of a morphing airfoil with auxetic structure. The advantages of the morphing airfoil with auxetic structure are (i) larger displacement with limited straining of the components and (ii) unique deformation characteristics, which produce a theoretical in-plane Poisson’s ratio of −1. Aluminum Alloy AL6061-T651 is considered in the design of all the structural elements. The compliance characteristics of the airfoil are investigated through a numerical model. The numerical results are observed to be in close agreement with the experimental results in the literature.

关键词： wing design     aerodynamic loads     morphing airfoil     auxetic structures     negative Poisson’s ratio    

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Seismic performance of fabricated continuous girder bridge with grouting sleeve-prestressed tendon composite

《结构与土木工程前沿（英文）》   页码 827-854 doi: 10.1007/s11709-023-0954-1

摘要： The seismic performance of a fully fabricated bridge is a key factor limiting its application. In this study, a fiber element model of a fabricated concrete pier with grouting sleeve-prestressed tendon composite connections was built and verified. A numerical analysis of three types of continuous girder bridges was conducted with different piers: a cast-in-place reinforced concrete pier, a grouting sleeve-fabricated pier, and a grouting sleeve-prestressed tendon composite fabricated pier. Furthermore, the seismic performance of the composite fabricated pier was investigated. The results show that the OpenSees fiber element model can successfully simulate the hysteresis behavior and failure mode of the grouted sleeve-fabricated pier. Under traditional non-near-fault ground motions, the pier top displacements of the grouting sleeve-fabricated pier and the composite fabricated pier were less than those of the cast-in-place reinforced concrete pier. The composite fabricated pier had a good self-centering capability. In addition, the plastic hinge zones of the grouting sleeve-fabricated pier and the composite fabricated pier shifted to the joint seam and upper edge of the grouting sleeve, respectively. The composite fabricated pier with optimal design parameters has good seismic performance and can be applied in high-intensity seismic areas; however, the influence of pile-soil interaction on its seismic performance should not be ignored.

关键词： seismic performance     continuous girder bridge     grouting sleeve-prestressed tendon composite connections     grouted sleeve connection     design parameters    

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多相复合陶瓷刀具材料的设计与制备

许崇海,艾兴

《中国工程科学》 2001年 第3卷 第3期   页码 71-74

摘要：

陶瓷材料的多相复合与计算机辅助设计是21世纪先进陶瓷材料的重要发展趋势。文章采用理论与实验相结合的方法，建立了多相复合陶瓷刀具材料力学性能与材料组分之间关系的数学模型，采用计算机辅助优 化设计技术求得材料的最优组分。在此基础上，利用热压技术制得一种Al2〇3-SiC-(W,Ti) C多相复合陶瓷刀具材料，该材料具有良好的综合力学性能。

关键词： 陶瓷刀具材料     多相复合     材料设计     模型     力学性能    

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Design of nanofibre interlayer supported forward osmosis composite membranes and its evaluation in fouling

《环境科学与工程前沿（英文）》 2022年 第16卷 第9期 doi: 10.1007/s11783-022-1550-7

摘要：

• A fine fibre (40–60 nm diameter) interlayer (~1 µm thickness) was electrospun.

关键词： Forward osmosis     Electro-spinning     Interfacial polymerisation     Fouling     Polyvinylidene fluoride    

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Multiscale RBF-based central high resolution schemes for simulation of generalized thermoelasticity problems

Hassan YOUSEFI, Alireza TAGHAVI KANI, Iradj MAHMOUDZADEH KANI

《结构与土木工程前沿（英文）》 2019年 第13卷 第2期   页码 429-455 doi: 10.1007/s11709-018-0483-5

摘要： In this study, average-interpolating radial basis functions (RBFs) are successfully integrated with central high-resolution schemes to achieve a higher-order central method. This proposed method is used for simulation of generalized coupled thermoelasticity problems including shock (singular) waves in their solutions. The thermoelasticity problems include the LS (systems with one relaxation parameter) and GN (systems without energy dissipation) theories with constant and variable coefficients. In the central high resolution formulation, RBFs lead to a reconstruction with the optimum recovery with minimized roughness on each cell: this is essential for oscillation-free reconstructions. To guarantee monotonic reconstructions at cell-edges, the nonlinear scaling limiters are used. Such reconstructions, finally, lead to the total variation bounded (TVB) feature. As RBFs work satisfactory on non-uniform cells/grids, the proposed central scheme can handle adapted cells/grids. To have cost effective and accurate simulations, the multiresolution–based grid adaptation approach is then integrated with the RBF-based central scheme. Effects of condition numbers of RBFs, computational complexity and cost of the proposed scheme are studied. Finally, different 1-D coupled thermoelasticity benchmarks are presented. There, performance of the adaptive RBF-based formulation is compared with that of the adaptive Kurganov-Tadmor (KT) second-order central high-resolution scheme with the total variation diminishing (TVD) property.

关键词： central high resolution schemes     RBFs     higher order accuracy     generalized thermoelasticity     multiresolution-based adaptation    

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Development of lunar regolith composite and structure via laser-assisted sintering

《机械工程前沿（英文）》 doi: 10.1007/s11465-021-0662-2

摘要： Aiming at the exploration and resource utilization activities on the Moon, in situ resource utilization and in situ manufacturing are proposed to minimize the dependence on the ground transportation supplies. In this paper, a laser-assisted additive manufacturing process is developed to fabricate lunar regolith composites with PA12/SiO2 mixing powders. The process parameters and composite material compositions are optimized in an appropriate range through orthogonal experiments to establish the relationship of process–structure–property for lunar regolith composites. The optimal combination of composite material compositions and process parameters are mixing ratio of 50/50 in volume, laser power of 30 W, scanning speed of 3500 mm/s, and scanning hatch space of 0.2 mm. The maximum tensile strength of lunar regolith composites reaches 9.248 MPa, and the maximum depth of surface variation is 120.79 μm, which indicates poor powder fusion and sintering quality. Thereafter, the mechanical properties of laser-sintered lunar regolith composites are implemented to the topology optimization design of complex structures. The effectiveness and the feasibility of this laser-assisted process are potentially developed for future lightweight design and manufacturing of the solar panel installed on the lunar rover.

关键词： in situ manufacturing     laser-assisted powder fusion process     mechanical properties     topological structure design    

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Ion conduction path in composite solid electrolytes for lithium metal batteries: from polymer rich to

Zhouyu ZHANG, Hao CHEN, Zhenglin HU, Shoubin ZHOU, Lan ZHANG, Jiayan LUO

《能源前沿（英文）》 2022年 第16卷 第5期   页码 706-733 doi: 10.1007/s11708-022-0833-9

摘要： Solid-state electrolytes (SSEs) can address the safety issue of organic electrolyte in rechargeable lithium batteries. Unfortunately, neither polymer nor ceramic SSEs used alone can meet the demand although great progress has been made in the past few years. Composite solid electrolytes (CSEs) composed of flexible polymers and brittle but more conducting ceramics can take advantage of the individual system for solid-state lithium metal batteries (SSLMBs). CSEs can be largely divided into two categories by the mass fraction of the components: “polymer rich” (PR) and “ceramic rich” (CR) systems with different internal structures and electrochemical properties. This review provides a comprehensive and in-depth understanding of recent advances and limitations of both PR and CR electrolytes, with a special focus on the ion conduction path based on polymer-ceramic interaction mechanisms and structural designs of ceramic fillers/frameworks. In addition, it highlights the PR and CR which bring the leverage between the electrochemical property and the mechanical property. Moreover, it further prospects the possible route for future development of CSEs according to their rational design, which is expected to accelerate the practical application of SSLMBs.

关键词： composite solid electrolytes     active filler/framework     ion conduction path     interphase compatibility     multilayer design    

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Experimental and statistical investigation of a new concrete-composite beam with encased polymer tube

Abdelmadjid SI SALEM,Souad AIT TALEB,Kamal AIT TAHAR

《结构与土木工程前沿（英文）》 2015年 第9卷 第2期   页码 154-162 doi: 10.1007/s11709-015-0296-8

摘要： A new concrete-composite beam with high mechanical performances to weight ratio is developed in this study. The proposed design technique consists to embed a cylindrical polymer tube wrapped by a GFRP Jacket in the mechanically ineffective concrete tensile zone. An experimental investigation is carried out on composite beams under bending loads until failure to evaluate the flexural capacity and the corresponding failure mechanisms. Based on the experimental results, statistical and preliminary reliability analyses using the FORM method are performed to assess the safety margin of the new beam. The confrontation between test and simulation results shows a satisfactory agreement, and represents a promising revelation regarding the improvement in terms of strength and ductility of such design compared to conventional reinforced concrete beams with traditional one.

关键词： design     GFRP-Jacket     polymer tube     test     reliability analysis    

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标题 作者 时间 类型 操作

Degradation of refractory organics in concentrated leachate by the Fenton process: Central compositedesign for process optimization

Senem Yazici Guvenc, Gamze Varank

期刊论文

Development of a multi-component drug from turmeric using central composite design

Xiaohang ZHANG,Shengnan HAN,Yan LI,Jianlan JIANG

期刊论文

Statistical modeling of radiolytic (

G. S. Muthu Iswarya, B. Nirkayani, A. Kavithakani, V. C. Padmanaban

期刊论文

Removal of malachite green from aqueous solution by sorption on hydrilla verticillata biomass using response surface methodology

R. RAJESHKANNAN, N. RAJAMOHAN, M. RAJASIMMAN

期刊论文

Trial design of arch bridge of composite box section with steel web-concrete flange

Jiangang WEI, Qingwei HUANG, Baochun CHEN,

期刊论文

Design of composite flywheel rotor

BAI Yue, GAO Qingjia, LI Haiwen, WU Yihui, XUAN Ming

期刊论文

Analysis and design of steel-concrete composite sandwich systems subjected to extreme loads

Kazi Md Abu SOHEL, Jat Yuen Richard LIEW, Min Hong ZHANG

期刊论文

Design concepts of an aircraft wing: composite and morphing airfoil with auxetic structures

P R BUDARAPU,Sudhir Sastry Y B,R NATARAJAN

期刊论文

Seismic performance of fabricated continuous girder bridge with grouting sleeve-prestressed tendon composite

期刊论文

多相复合陶瓷刀具材料的设计与制备

许崇海,艾兴

期刊论文

Design of nanofibre interlayer supported forward osmosis composite membranes and its evaluation in fouling

期刊论文

Multiscale RBF-based central high resolution schemes for simulation of generalized thermoelasticity problems

Hassan YOUSEFI, Alireza TAGHAVI KANI, Iradj MAHMOUDZADEH KANI

期刊论文

Development of lunar regolith composite and structure via laser-assisted sintering

期刊论文

Ion conduction path in composite solid electrolytes for lithium metal batteries: from polymer rich to

Zhouyu ZHANG, Hao CHEN, Zhenglin HU, Shoubin ZHOU, Lan ZHANG, Jiayan LUO

期刊论文

Experimental and statistical investigation of a new concrete-composite beam with encased polymer tube

Abdelmadjid SI SALEM,Souad AIT TALEB,Kamal AIT TAHAR

期刊论文